Sunday, June 12, 2011

3.4 I can recall the products of complete and incomplete combustion of alkanes


Description: Machine generated alternative text: Combustion
As you know, the fuels we get from crude oil are called
hydrocarbons.
Petrol is a mixture of hydrocarbons.
Can you remember which 2 elements make up
a hydrocarbon? Petrol contains octane. Can you
guess how many carbon atoms there are in octane?
When we burn a fuel, the reaction is called combustion.
The fuel reacts with oxygen gas from the air and heat is given out.
But what is made in the reaction? You can find out
in the next experiment:
Experiment 11.3 Products of combustion
Set up the apparatus as shown
Let it run until you see some
changes in the U-tube
and in the limewater.
• What do you see inside the U-tube?
• WhQt happens to the limewater?
• Which gas makes limewater go milky?
• Why should you repeat the experiment with just air
being sucked through?
• What is your conclusion?
When hydrocarbons burn, they are oxidised.
We get carbon dioxide and water formed (never hydrogen!):
hydrocarbon + oxygen carbon dioxide + water
Incomplete combustion
There is only a small amount of oxygen inside a car engine.
There is not enough to turn all the carbon in the hydrocarbons
into carbon dioxide. Some carbon monoxide, a toxic gas,
is also made.
Catalytic converters on exhausts, once warmed up, can turn
carbon monoxide into carbon dioxide.
Sometimes fuels burn with a smoky flame. Incomplete
combustion means that carbon itself is given off as soot.
Particles from diesel are also polluting the air in our cities.
Unburnt hydrocarbons in particulates can cause cancer.
Combustion is a useful reaction
- to water pump
(to suck the
gases
through the
apparatus)
ti
tlammable
liqukis
liquid fuel
(such as hexane)
crushed ice blue colbalt chloride
and water paper (which turns
pink in water)
Carbon monoxiae is given on irom car
exhausts. This gas reacts with
haemoglobin. It stops your blood carrying
oxygen around your body. This toxic gas
can kill unsuspecting people when given
off by faulty gas heaters.
147
Description: Machine generated alternative text: Don’t try to learn these equations! Practise
working them Out for a wide range of
different hydrocarbons. You will find
guidance on how to work out the ethane
equation in Chapter 5. page 38.  -
19.4 As weÐI as all the other poisonous or
cancer-causing compounds, cigarette smoke
contains carbon monoxide due to incomplete
combustion.
·         Saturated hydrocarbons are called ALKANES
·         Small chain ALKANES are used as fuels
3.       The reaction is called COMBUSTION REACTION
4.       The word equation for  this chemical reaction is :
fuel (E.G. PROPANE) + OXYGEN → WATER + CARBON DIOXIDE + ENERGY (heat, light, sound)
5.       If there is insufficient oxygen then the word equation is:
fuel (PROPANE) + OXYGEN → CARBON DIOXIDE + CARBON MONOXIDE + WATER + ENERGY (heat, light, sound)
6.       The problem with this reaction is that CARBON MONOXIDE is produced this gas is a POISONOUS/HARMFUL GAS to the human body (see objective 5.11)
7.       Where can you find incomplete combustion?
8.       What is used to reduce the harmful products from incomplete combustion?
9.       During incomplete combustion a smoky flame is often seen, explain this observation
10.   Describe the two chemical tests for water
11.   Describe the chemical test for carbon dioxide gas
12.   Describe a physical test for water
Extn: write a balanced equation (with state symbols) for the combustion of propane gas

Sunday, May 22, 2011

3.2 and 3.3 I can recall the general formula and displayed formulae of alkanes


What is the general formula for alkanes?
Cn Hn+2 (n represents the number of carbon atoms)

Describe and explain the trend in boiling point.
As the chain gets longer/bigger (it has strong intermolecular forces) they have higher boiling points.
Because it is harder to separate the bonds.

METHANE


ETHANE


PROPANE


BUTANE


PENTANE



DIFFERENT DISPLAYED FORMULA OF PENTANE

Sunday, May 15, 2011

5.13 I can describe catalytic cracking of long-chain hydrocarbons

Description: DF43D2BB-25CB-4E99-A590-80DD2A294077.png

2004_cracking_liquid_paraffin.mpg



1. Why should you take the end of the delivery tube out of water before you stop heating?
To prevent 'suck back' which can cause rapid change in volume and break the testube (explosion)
2. Name the catalyst for cracking paraffin.
Aluminium Oxide
3. What method is used to collect the gas? Describe the reason why/process.
Over water. The gas doesn't dissolve in water, therefore it is the most suitable way to collect the gas.
4.  What is the process to distill the crude oil?
Cracking
5. Catalysts are used in this experiment. What is the purpose of it?
To speed up the experiment
6.
7.
8.

5.12 I can recall the problems associated with the fractional distillation of crude oil

Description: 3B108186-775D-4C09-B664-A4D8CAC4BB7A.png

a) When the crude oil under goes FRACTIONAL DISTILLATION there are too many LONG chain hydrocarbons (e.g. BITUMEN) produced and not enough SHORT chain hydrocarbons (e.g. REFINARY GAS).

b) To solve these problems the LONG chain hydrocarbons undergo a chemical reactions called CRACKING/THERMAL DECOMPOSITION.


5.11 I can recall how nitrogen oxides are formed in car engines

Fight For Your Right To Clean Air

(highlight to view the answers)
a.       Write the general equation for the combustion of a fuel
glucose + oxygen -> carbon dioxide + water + ENERGY
b.      During combustion the nitrogen in air can react to form what gases?
NO (nitrogen oxide) and NO2 (nitrogen dioxide)
c.       What condition is necessary for this reaction to take place?
High temperature
d.      In what common object is this condition found?
Car
e.      Why is this condition needed for nitrogen to react?
Because high temperature can break the strong triple covalent bonds
f.        What are the dangers of the products from this reaction?
HNO3, it makes acid rain (this is when NO or NO2 reacts with water)

5.10 I can recall the problems associated with incomplete combustion

Carbon Monoxide Poisoning / Educational Video


Carbon Monoxide Poisoning


1.       What are the properties of carbon monoxide?
        Carbon monoxide is a poisonous gas which is colourless, odorless and tasteless

2.       Explain how carbon monoxide is formed.
        Carbon monoxide is formed when there is not enough oxygen available during the combustion process.
        This means that carbon monoxide is formed when the combustion is incompleted.

3.       Explain why carbon monoxide is poisonous
        Carbon monoxide is very poisonous because once you are exposed to it, carbon monoxide gets attached to your haemoglobin before oxygen does.  Therefore, it can cause serious problems.

5.9 I can describe the trend in boiling point and viscosity of the main fractions

a.       What is the trend in boiling point of the fractions?
        The higher in the column, the lower the boiling point. This is because fractions which are located in higher place have small molecules (structure)
b.      Define viscosity (source your definition)
        Viscosity describes how well the liquid flows. E.g Water and ethanol have high viscosity. Honey has low (REMEMBER THE "SLOW") viscosity

c.       What is the trend in viscosity of the fractions?
        Viscosity of the fractions gets lower as it goes down the column

d.      What is the trend in colour of the fractions?
        The lower in the column, the darker

e.      Why is crude oil separated into fractions?
        Because each fractions have different boiling points

f.        What process is used to separate crude oil into fractions?
        Fractional distillation is used to seperate the crude oil into different fractions

g.       What physical property allows this process to work?
        Different boiling points for each fractions

Description: Machine generated alternative text: small molecules
crude oil
is heated
and enters
as a vapour
.
o
0
I petroleum
gases
(such as propane
and butane)
petrol
(gasoline)
• low boiling point (volatile)
. light in colour
easy to light and
bum weU (flammable)
. runny
large molecules
. high boiling point
. dark in colour
. hard to light
• viscous or thick
(if still a liquid at
room temperature
— bitumen is a solid)
low
temperature
I
(paraffin)
kerosine
diesel
lubricating
oil
I heavy fuel
oil
high
temperature
360C
I
bitumen